Examinando por Materia "Soil contamination"

Mostrando 1 - 4 de 4

Ecological and carcinogenic risk assessment of potentially toxic elements in rangelands and croplands around Lake Junin (Peru): Integrating remote sensing, machine learning, and land cover segmentation
(Elsevier, 2025-08-27) Pizarro Carcausto, Samuel Edwin; Requena Rojas, Edilson Jimmy; Barboza, Elgar; Peña Elme, Eunice Dorcas; Arias Arredondo, Alberto Gilmer; Ccopi Trucios, Dennis
The Junín Lake basin, a critical high-altitude ecosystem in the central Peruvian Andes, faces severe contamination from potentially toxic elements (PTEs) driven by mining activities, agriculture, and urbanization. This study evaluates the spatial distribution, ecological risk, and human health implications of 14 heavy metals, metalloids, and trace elements in surface soils surrounding the lake. Using 211 soil samples, we integrated remote sensing, land cover classification, and Random Forest machine learning models with spectral, edaphic, topographic, and proximity-based environmental covariates to predict contamination patterns and assess risk. Results reveal extreme contamination, with arsenic (As), lead (Pb), cadmium (Cd), and zinc (Zn) concentrations exceeding ecological thresholds by over 100-fold in agricultural zones. Ecological risk assessments using contamination degree (mCD), pollution load index (PLI), and risk index (RI) indicated that over 99 % of the study area exhibits very high to ultra-high contamination levels. Human health risk analysis identified unacceptable carcinogenic risks from As, Pb, and Cr across adult and pediatric populations, with arsenic presenting the greatest concern. The integration of geospatial tools and machine learning enabled precise identification of contamination hotspots and vulnerable land cover types, demonstrating the value of AI approaches for monitoring contaminated territories. These findings underscore the urgent need for coordinated environmental management, targeted remediation strategies, and community-based monitoring to protect public health and preserve Andean ecosystem integrity.
Efectos fisiológicos del cadmio en cuatro genotipos de cacao propagados mediante estaquillas enraizadas
(Universidad Nacional Agraria de la Selva - UNAS, 2025-11-05) Paz Urrelo, Jorge Luis; Pocomucha Poma, Vicente Serapio
El objetivo de la presente investigación fue estudiar los efectos del Cd en cuatro genotipos de cacao en términos de concentración de pigmentos de clorofila, asimismo evaluar el factor de traslocación del Cd en plantas de cacao obtenidos mediante propagación clonal mediante la técnica enraizamiento de estaquillas. El material vegetal utilizado en el presente trabajo de investigación fueron genotipos procedentes de los clones CCN 51, ICS 39, IMC 67 y TSH 565. El sustrato fue inoculado con tres dosis de Cd (0, 6 y 12 ppm). La fuente de Cd fue el hidrato de cloruro de Cadmio (CdCl2H2O). Se utilizó un Diseño Completamente al azar (DCA) con arreglo factorial de 4 x 3 factores, con 3 repeticiones, donde cada tratamiento estuvo formado por 4 plántulas de cacao obtenidas por enraizamiento de estaquillas, teniéndose en total 36 unidades experimentales. El análisis estadístico reveló que las plantas procedentes del genotipo CCN 51 fueron las que mostraron mayor tolerancia al metal pesado, aún en las dosis altas de Cd, debido a un aumento en el contenido de clorofila. Por otra parte, nuestros hallazgos advierten que el genotipo ICS 39 inoculado a la dosis media de Cd (6 ppm) presentó el factor de traslocación (FT) más alto (4.16). En contraste el genotipo CCN 51, evidenció el menor FT cuando fue expuesto a la dosis más alta de Cd. Estos hallazgos permitirán comprender el comportamiento de las plantas de cacao producidas por enraizamiento de estaquillas ante el estrés por Cd en términos de fisiológicos, siendo esta investigación un insumo más para profundizar estudios basados en los efectos de los metales pesados en cultivos de gran importancia económica como lo es el cacao.
Geospatial distribution of cadmium in soil profiles of cacao (Theobroma cacao L.) plantations in the Peruvian Amazon basin
(Frontiers Media S.A., 2026-02-25) Vallejos Torres, Geomar; Chuchon Remon, Rodolfo Juan; Gaona Jimenez, Nery; Marín, César; Cruz Luis, Juancarlos Alejandro; Solórzano Acosta, Richard Andi
Introduction: Cacao plants can translocate heavy metals from the soil to vegetative tissues, potentially leading to concentrations that exceed maximum permissible limits. This study aimed to analyze the geospatial distribution of cadmium (Cd) in soil profiles of cacao (Theobroma cacao L.) plantations in the Amazon basin of Peru. Methods: The research was conducted in the localities of Jeberillos, Arahuante, and Luz del Oriente, within the department of Loreto. In each locality, 10 plots of 100 m² were selected, totaling 30 plots. Cd concentrations and physicochemical soil parameters were evaluated. Results: In cacao soils from Luz del Oriente at 0–30 cm depth, Cd concentrations averaged 1.11 ± 0.26 mg.kg⁻¹, representing the highest values; whereas the lowest average was recorded in Arahuante at the same depth, with 0.61 ± 0.15 mg.kg⁻¹. Cd levels in Luz del Oriente cacao soils (0–30 cm) were above the average among all localities, while Jeberillos and Arahuante soils showed comparatively lower Cd levels. Discussion: Overall, Cd in cacao soils was found to be strongly associated with edaphic factors such as pH, texture, effective cation exchange capacity (CEC), and cation composition. The maps represented the spatial distribution of the metal and guided the identification of potential accumulation zones. These findings provide essential insights for guiding agricultural management decision-making, environmental monitoring, and metal contamination risk assessment in cacao-growing areas and other agrarian systems in the Peruvian Amazon basin.
Occurrence, sources, and ecological risk of polycyclic aromatic hydrocarbons (PAHs) in rice field soils of northwestern Peru
(Elsevier B.V., 2026-02-04) Culqui Gaslac, Cristian; Tineo Flores, Daniel; Fernandez Jibaja, Jorge Antonio; Alvarez Robledo, Yeltsin Abel; Garcia Frias, Larry Dustin; Mendoza Merino, Jani Elisabet; Taboada Mitma, Víctor Hugo; Cruz Luis, Juancarlos Alejandro; Rojas Briceño, Nilton B.; García, Ligia; Zirena Vilca, Franz; Goñas Goñas, Malluri
Polycyclic aromatic hydrocarbons (PAHs) are organic contaminants that pose significant risks to human health and ecosystems. This study investigated the occurrence, sources, and ecological risks of PAHs in rice paddy soils from northwestern Peru. Ninety-seven soil samples were collected at a depth of 30 cm across three altitudinal zones, four phenological stages, and two agronomic management practices. Quantification was performed using ultra-high-performance liquid chromatography coupled with fluorescence detection (UHPLC-FLD). Source apportionment was conducted through rotated principal component analysis combined with multiple linear regression. Ecological risk was assessed using organic carbon normalization and the mean effects range-median quotient (M-ERM-Q) method, while carcinogenic potential was estimated using the toxic equivalent factor (TEQCARC). Total PAHs ranged from 22.02 to 130.55 ng g⁻¹ (mean: 55.26 ng g⁻¹); LMW PAHs averaged 37.38 ng g⁻¹, exceeding HMW PAHs (17.88 ng g⁻¹). No significant differences were observed among altitudinal zones, phenological stages or agronomic practices (p > 0.05). The predominant sources of PAHs were attributed to vehicular emissions (52.3%), petroleum and biomass combustion (42.1%), and coal combustion (5.4%). Ecological risk assessment revealed low contamination levels below established safety thresholds (CEC <290 μg g⁻¹), consistent with the carcinogenic risk estimated through TEQCARC (0.0083 to 18.7483 ng BaPeq g⁻¹). This study provides the first comprehensive evaluation of PAHs contamination in rice paddy soils in Peru and underscores the influence of altitude and agricultural practices, emphasizing the need for further research on pollution sources, impacts on crop productivity, and potential risks to human health.