Examinando por Materia "Cadmio"

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Antagonistic interaction between zinc and cadmium in cocoa (Theobroma cacao L. var. CCN-51) seedlings amended with rock phosphate
(Frontiers Media SA, 2026-02-12) Díaz Chuquizuta, Henry; Malca Quezada, María Esmilda; Vallejos Torres, Geomar; Cuevas Gimenez, Juan Pablo; Huamaní Yupanqui , Hugo Alfredo; Sánchez Ojanasta, Martín; Solórzano Acosta, Richard Andi; Martínez Zapata, Boris Guillermo
Introduction: In the San Martın region, several studies have reported Cd concentrations in surface soils approaching the upper limit (UL), with mean values ranging from 0.27 to 1.351 mg·kg- ¹. Methods: Cadmium (Cd) transfer to Theobroma cacao (CCN-51) seedlings was evaluated under 12 factorial combinations of phosphate rock (RFP) and foliar zinc sulphate (ZnSO4) applications, using relative uptake (foliar Cd/soil Cd) as the primary response variable. Results: The treatment showing the highest Cd uptake was T4, defined as RFP = 0 mg·kg-1 and ZnSO4 = 527.80 mg·plant-1, with a value of 53.12. The observed range in relative uptake was 33.08 units, indicating substantial variation among management combinations. At the factor-level analysis, the high RFP treatment (114.55 mg·kg- ¹) was associated with an average reduction of approximately 26.5% in relative uptake and lower within-group variability compared to the 0 mg·kg- ¹ level. Interaction plots indicated that the effect of ZnSO4 on nutrient uptake depended on RFP level, with a descending response profile at high RFP concentrations. In parallel, soil correlation analyses identified available phosphorus and pH as the principal modulators of Cd transfer from soil to plant. Leaf-level principal component analysis showed that Zn and K were projected in the opposite direction to P2O5 and Cd, consistent with an ionic balance mechanism regulating Cd accumulation, and achieved an overall classification accuracy of approximately 81%, thereby confirming multivariate separability among treatments. Discussion: Collectively, these integrated results support identifying T4 as the treatment with the highest Cd uptake within the evaluated set. Accordingly, the presence of Zn²+–Cd²+ antagonism can be asserted; however, its expression is strongly influenced by soil pH and, most critically, by the availability of phosphorus derived from RFP.
Determinación de plomo y cadmio en frutos de Mangifera indica L. (mango) cercanos a pozos de oxidación
(Universidad Nacional de Trujillo - Facultad de Ciencias Biológicas, 2026-01-29) Alarcon Cruz, Neidi; Peláez Gonzales, Romario Anibal; Chico Ruíz, Julio Roger; Campos Ruiz, Joseph; Campos Ruiz, Sanderson Narcizo; Calle Iparraguirre, Nander Oriol; García Carrasco, Elfer
Los metales pesados constituyen una de las principales fuentes de contaminación ambiental debido a su persistencia, bioacumulación y efectos adversos sobre los ecosistemas y la salud humana. El presente estudio tuvo como objetivo determinar las concentraciones de plomo (Pb) y cadmio (Cd) en frutos de Mangifera indica L. cultivados en áreas adyacentes a pozos de oxidación en el distrito y provincia de Jaén, Perú. La cuantificación de los metales se realizó mediante espectrofotometría de absorción atómica, siguiendo la normativa USEPA (1996) y el método 3052. Los resultados indicaron que el 33,3 % de las muestras superaron los límites máximos permisibles de Pb y el 3,33 % excedieron los valores establecidos para Cd, conforme al Codex Alimentarius, la Unión Europea y la legislación rusa. Asimismo, se observó mayor concentración de Pb en frutos de la parte inferior de la copa y de Cd en la zona media. En conclusión, los frutos evaluados no son aptos para consumo humano, representando un riesgo potencial para la salud pública.
Estudio de vigilancia tecnológica en remediación de suelos de cultivos contaminados por cadmio
(Instituto Nacional de Innovación Agraria, 2021-07) Cayetano Terrel, Paolo; Peña Pineda, Karla Mónica; Olivarez Rivera, Evelyn Lissete; Vargas Cisneros, Sandra Marilia
El presente estudio de vigilancia tecnológica en remediación de suelos de cultivos contaminados por cadmio, tiene como objetivo dar a conocer las nuevas tecnologías, tendencias y líderes tecnológicos enfocados en este tema. En este trabajo se identifican las principales patentes tecnológicas en dos áreas de interés: a) La remoción y disminución de cadmio mediante componentes químicos y b) La remoción y disminución de cadmio mediante componentes biológicos. Este estudio está dirigido a los investigadores, gestores de la I+D+i y actores del Sistema Nacional de Innovación Agraria (SNIA) para una adecuada toma de decisiones orientadas a desarrollar nuevas propuestas de investigación y desarrollo de tecnologías en el sector agrario del Perú.
Geospatial distribution of heavy metals in rice soils of northwestern Peru
(Nature Portfolio (Springer Nature), 2025-08-21) Tarrillo Julca, Ever; Arce Inga, Marielita; Torres Herrera, Pedro Antonio; Tineo Flores, Daniel; Taboada Mitma, Victor Hugo; Cruz Luis, Juancarlos Alejandro; Rojas Briceño, Nilton B.; Atalaya Marin, Nilton; Gómez Fernández, Darwin; Goñas Goñas, Malluri
The presence of heavy metals in agricultural soils poses a threat to the development of sustainable agriculture and ensuring food security. The objective of this study was to evaluate the geospatial distribution of heavy metals in rice-growing soils within the Amojú River Basin, Jaen, Peru. Ninety-five soil samples were collected randomly, covering four altitudinal ranges, namely, very low (374–450 m above sea level (m a.s.l.)), low (450–571 m a.s.l.), medium (571–701 m a.s.l.) and high altitudes (701–1,034 m a.s.l.), and different agronomic management stages, including four phenological phases (seedling, tillering, filling and ripening) and two agricultural practices (resting and stubble burning). The evaluation was conducted via physicochemical analysis, the single-factor pollution index, and spatial interpolation techniques through the empirical Bayesian kriging (EBK) method. The results indicated that the contents of cadmium (Cd) and chromium (Cr) exceed the limits established in the Environmental Quality Standards (EQSs) for agricultural soils, with maximum Cd and Cr concentrations of 2 and 21 mg kg ⁻¹, respectively, mainly in very low-altitude areas (374–450 m a.s.l.). The single-factor pollution index results indicated slight Cd contamination and intense Cr contamination. Likewise, high levels of arsenic (As), Cd, and Cr were detected in soils managed via stubble burning, reaching 2, 2, and 16 mg kg ⁻¹, respectively. The highest Cr concentrations were located in the northeastern and western parts of the study area, whereas the highest Cd concentrations occurred in the northeastern and southwestern parts. These concentrations may be associated with potential contamination sources, with the use of phosphate fertilizers, water for cultivation, and soil erosion as key contributors. This study highlights the potential risk to rice productivity and crop safety, emphasizing the importance of implementing sustainable agricultural practices and monitoring strategies for heavy metals in soils associated with crops.
Global studies of cadmium in relation to Theobroma cacao: A bibliometric analysis from Scopus (1996 -2020)
(Universidad Nacional de Trujillo, 2021-12-15) García, Ligia; Angulo Castro, Fabio; Hernández Amasifuen, Angel David; Corazon Guivin, Mike Anderson; Alburquerque Vásquez, Javier; Guerrero Abad, Juan Carlos; Arellanos, Erick; Veneros Guevara, Jaris Emmanuel; Rojas Briceño, Nilton B.; Chavez Quintana, Segundo G.; Oliva Cruz, Manuel
En el año 2014, la Unión Europea impuso estándares máximos de tolerancia en cadmio, para la importación de productos a base de cacao, causando preocupación en los países. Se analizó estudios globales referidos a investigaciones en Theobroma cacao, relacionados con la actividad del cadmio en la atmósfera. Se utilizaron análisis bibliométricos en los programas R y VOSviewer, para examinar 64 documentos publicados en la base de datos Scopus según palabras clave. Se identificaron 811 palabras clave en coocurrencias de términos, 5 grupos temáticos en acoplamiento bibliográfico, 20 instituciones como afiliaciones más importantes, 20 países de procedencia de autores corresponsales, 112 instituciones en red de coautoría de los cuales 5 están en documentos primarios, y dos grupos en similaridad temática en co-citación de documentos. Estados Unidos lidera la producción científica con 11 documentos, seguido de Colombia (8) y Ecuador (7). En 1996 se registró el primer artículo científico para la red, con incrementos de hasta 11 publicaciones al 2020. En conclusión, se evidencia la necesidad de fortalecer y crear más redes de investigaciones entre países, instituciones, autores y coautores. Se espera que los resultados permitan desentrañar de manera integral la trayectoria de investigaciones cadmio-cacao, al tiempo que arrojen nuevas investigaciones prospectivas.
Influence of cadmium and arbuscular mycorrhizae on growth and chlorophyll content in Theobroma cacao and Theobroma grandiflorum Plants
(John Wiley & Sons Ltd., 2026-01-20) Vallejos Torres, Geomar; García Vallejos, Noellia; Gaona Jimenez, Nery; Lozano, Andi; Lozano Carranza, Carlos M.; Alva Arévalo, Alberto; Puicón Niño de Guzmán, Víctor Humberto; Saavedra Ramírez, Jorge; Tuesta Hidalgo, Juan C.; Tuesta Hidalgo, Oscar A.; Valdez Andía, Manuel Jesús; Ordoñez Ruiz, Karina M.; Baselly Villanueva, Juan Rodrigo
Inoculation of arbuscular mycorrhizal fungi (AMF) has important benefits, not only for plant growth but also for reducing Cd absorption in Theobroma plants. This study aimed to investigate the influence of cadmium (Cd) and arbuscular mycorrhizae (AM) on growth and chlorophyll content (CC) in Theobroma plants. This experiment had a 3 × 2 × 2 factorial design with species of Theobroma cacao and Theobroma grandiflorum, AMF inoculation (mycorrhizal control and AMF inoculation), and Cd addition (0, 1, and 3 mg kg⁻¹), arranged in a completely randomized design with three repetitions. The AMF inoculum consisted of applying 1500 units to each seedling. The results showed that the Cd content decreased in the stems with AMF treatment for T. cacao as well as in the soil, showing significant differences in both variables. However, a reduction of Cd could also be observed in T. grandiflorum stems without significant differences with Cd in the soil. The height, diameter, root biomass, and leaf area (LA) of the Theobroma plants increased in most of the treatments studied in comparison with treatments that received Cd, as did CC. The AMFs inoculated into Theobroma plants induced higher CC in leaves. Likewise, T. cacao presented a higher value in morphology and a lower Cd concentration in soil and shoots.
Spatial assessment of heavy metal contamination in agricultural soils of the lower Chancay–Huaral valley, Peru
(Wiley, 2026-05-29) Samaniego Vivanco, Tomás Daniel; Ramirez Aparicio, Jorge Adrian; Solórzano Acosta, Richard Andi
Soil contamination by heavy metals (HMs) poses a potential threat to agricultural productivity and food security, particularly in rapidly developing coastal regions. This study evaluates the spatial distribution and contamination levels of cadmium (Cd), copper (Cu), lead (Pb), zinc (Zn), and manganese (Mn) in agricultural soils from the Huaral, Chancay, and Aucallama districts of the Lima region, Peru, an area undergoing urban expansion, mining concessions, and the establishment of a new international port. A total of 88 soil samples were analyzed for metal concentrations using microwave plasma atomic emission spectrophotometry (MP-AES), along with key physicochemical properties. Geostatistical interpolation techniques, including ordinary kriging (OK) and cokriging (CK), were applied to generate spatial prediction maps for each element. The geo-accumulation index (Igeo) and contamination factor (CF) were used to determine the contamination status. Mean Igeo values ranged from −0.59 to −0.46, while mean CF values ranged from 1.09 to 1.21, indicating generally unpolluted to moderately polluted conditions. Although maximum values reached 1.41 for Igeo and 4.21 for CF, these were spatially localized. Results revealed that most metal concentrations remained below the Peruvian Environmental Quality Standards for agricultural soils, suggesting predominantly natural geochemical origins. However, a small proportion of samples showed slight and localized exceedances (4.54% for Cd and 3.41% for Mn). For elements not regulated under national standards, international guidelines were considered, further supporting the absence of widespread anthropogenic contamination. Higher concentrations of Cd, Cu, Zn, Pb, and Mn were spatially clustered in the north-central sector of the study area, suggesting responses to soil properties such as pH, texture, and moisture. Notably, areas of higher concentration did not coincide with zones of higher contamination indices, indicating limited anthropogenic influence. However, proximity to urban expansion, mining activities, and port infrastructure highlights the need for continuous soil monitoring to prevent accumulation and ensure agricultural sustainability.
Weed Species Associated with Cacao Cultivation Exhibiting Phytoremediation Potential for Cadmium and Lead: A Study Based on Bioconcentration and Translocation Factors
(Tech Science Press, 2026-06-29) Romero Chávez, Lorena Estefani; Calero Rios, Emilee Nahomi; Aldava Pardave, Uriel; Ottos Díaz, Elvis; Salgado Veramendi, Noelito; Huerto Pajuelo, Eldhy Sianina; Ibarra Porras, Carolina del Carmen; Solórzano Acosta, Richard Andi
The exploration and identification of spontaneous weed species in heavy metal–contaminated soils represent a relevant approach for understanding the role and their potential application in phytoremediation. In cacao cultivation, cadmium contamination poses a significant risk due to the restrictions established for soils and cacao-derived products, thereby threatening productive sustainability and export viability. The objective of this study was to identify weed species associated with cacao cultivation exhibiting accumulation patterns and phytoremediation potential for Cd and Pb, through the assessment of biomass production and the bioconcentration factor (BCF) and translocation factor (TF), in natural conditions. Soil samples were collected from seven cacao-growing zones, and the site with the highest Cd concentration (1.65 mg kg−1) was selected, where ten dominant weed species were identified and evaluated. Significant interspecific differences were observed in biomass production and in Cd and Pb concentrations (p < 0.05). Talinum paniculatum exhibited the highest total biomass (6.15 g) and the highest TF for Cd, whereas Cyperus aggregatus showed the greatest total Cd accumulation (2.68 mg kg−1). BCF and TF values enabled the identification of species with accumulation patterns consistent with Cd phytoextraction (T. paniculatum, C. aggregatus, Pseudelephantopus spiralis, Bidens riparia, Euphorbia heterophylla, and Malvastrum coromandelianum) and with phytostabilization (Ocimum campechianum). For Pb the observed patterns were consistent with potential phytoextractive behavior in B. riparia, P. spiralis, E. heterophylla, Hilleria latifolia, and Acalypha stachyura. Although these results do not constitute functional evidence of remediation, they describe heavy metal accumulation and translocation patterns in native weed species, providing a technical basis for the design of future experimental trials aimed at the sustainable remediation of contaminated soils.